Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms

Allylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the allylation. Herein, we report a unique transition...

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Detalles Bibliográficos
Autores principales: Deng, Guogang, Duan, Shengzu, Wang, Jing, Chen, Zhuo, Liu, Tongqi, Chen, Wen, Zhang, Hongbin, Yang, Xiaodong, Walsh, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8222226/
https://www.ncbi.nlm.nih.gov/pubmed/34162867
http://dx.doi.org/10.1038/s41467-021-24027-6

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