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Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites

A novel Graphene oxide/Laponite RD/Chitosan ternary composite was synthesized by sol-gel method and freeze-drying method. The Laponite RD was silanized by 3-aminopropyltriethoxysilane (APTES). Graphene oxide (GO) was prepared by an improved Hummers method. Under the acidic conditions, self-assembly...

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Detalles Bibliográficos
Autores principales: Du, Wenjie, Ma, Rui, Liu, Zhiyan, Yang, Gang, Chen, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8230705/
https://www.ncbi.nlm.nih.gov/pubmed/34207982
http://dx.doi.org/10.3390/ma14123224
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author Du, Wenjie
Ma, Rui
Liu, Zhiyan
Yang, Gang
Chen, Tao
author_facet Du, Wenjie
Ma, Rui
Liu, Zhiyan
Yang, Gang
Chen, Tao
author_sort Du, Wenjie
collection PubMed
description A novel Graphene oxide/Laponite RD/Chitosan ternary composite was synthesized by sol-gel method and freeze-drying method. The Laponite RD was silanized by 3-aminopropyltriethoxysilane (APTES). Graphene oxide (GO) was prepared by an improved Hummers method. Under the acidic conditions, self-assembly recombination was realized by electrostatic interaction between modified Laponite RD and GO. The results from Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy confirmed that the modified Laponite RD was successfully compounded with GO, and the composite is laminated and stacked. The results from BET (Brunauer–Emmett–Teller) methods found that the BET-specific surface area of the hybrid aerogel significantly increased with the increase of the doping content of the composite, and the specific surface area of the aerogel composite with 20% doping content reached 81 m(2)/g. The structure of aerogel is porous, and there are numerous holes in the interior, which is closely related to adsorption properties. Thermogravimetric analysis (TG) test was used to explore the change of thermal properties of hybrid aerogel materials, and it was found that the addition of composite increased the initial decomposition temperature and thermal stability of hybrid aerogel. Finally, the potential applications of aerogel were tested, such as methylene blue adsorption and CO(2) adsorption.
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spelling pubmed-82307052021-06-26 Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites Du, Wenjie Ma, Rui Liu, Zhiyan Yang, Gang Chen, Tao Materials (Basel) Article A novel Graphene oxide/Laponite RD/Chitosan ternary composite was synthesized by sol-gel method and freeze-drying method. The Laponite RD was silanized by 3-aminopropyltriethoxysilane (APTES). Graphene oxide (GO) was prepared by an improved Hummers method. Under the acidic conditions, self-assembly recombination was realized by electrostatic interaction between modified Laponite RD and GO. The results from Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy confirmed that the modified Laponite RD was successfully compounded with GO, and the composite is laminated and stacked. The results from BET (Brunauer–Emmett–Teller) methods found that the BET-specific surface area of the hybrid aerogel significantly increased with the increase of the doping content of the composite, and the specific surface area of the aerogel composite with 20% doping content reached 81 m(2)/g. The structure of aerogel is porous, and there are numerous holes in the interior, which is closely related to adsorption properties. Thermogravimetric analysis (TG) test was used to explore the change of thermal properties of hybrid aerogel materials, and it was found that the addition of composite increased the initial decomposition temperature and thermal stability of hybrid aerogel. Finally, the potential applications of aerogel were tested, such as methylene blue adsorption and CO(2) adsorption. MDPI 2021-06-11 /pmc/articles/PMC8230705/ /pubmed/34207982 http://dx.doi.org/10.3390/ma14123224 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Du, Wenjie
Ma, Rui
Liu, Zhiyan
Yang, Gang
Chen, Tao
Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites
title Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites
title_full Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites
title_fullStr Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites
title_full_unstemmed Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites
title_short Study on the Adsorption Properties of Graphene Oxide/Laponite RD/Chitosan Composites
title_sort study on the adsorption properties of graphene oxide/laponite rd/chitosan composites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8230705/
https://www.ncbi.nlm.nih.gov/pubmed/34207982
http://dx.doi.org/10.3390/ma14123224
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