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Synthesis and single-molecule magnet properties of a trimetallic dysprosium metallocene cation
The dimetallic fulvalene-bridged dysprosium complex [{Dy(Cp*)(μ-BH(4))}(2)(Fv(tttt))] (1, Cp* = C(5)Me(5)) is converted into the trimetallic borohydride-bridged species [{Dy(Cp*)(Fv(tttt))}(2)Dy(μ-BH(4))(3)] (2). In turn, 2 is reacted with a silylium electrophile to give [{Dy(Cp*)(μ-BH(4))(Fv(tttt))...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8240697/ https://www.ncbi.nlm.nih.gov/pubmed/34085074 http://dx.doi.org/10.1039/d1cc02139g |