Protected amino acids as a nonbonding source of chirality in induction of single-handed screw-sense to helical macromolecular catalysts

Chiral nonbonding interaction with N-protected amino acid methyl esters used as chiral additives in achiral solvents allows dynamic induction of single-handed helical conformation in poly(quinoxaline-2,3-diyl)s (PQX) bearing only achiral substituents. Ac-l-Pro-OMe, for instance, allows induction of...

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Detalles Bibliográficos
Autores principales: Ikeda, Shoma, Takeda, Ryohei, Fujie, Takaya, Ariki, Naoto, Nagata, Yuuya, Suginome, Michinori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246299/
https://www.ncbi.nlm.nih.gov/pubmed/34257881
http://dx.doi.org/10.1039/d1sc01764k

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