Cargando…

Intermolecular Hydroaminoalkylation of Alkynes

Intermolecular hydroaminoalkylation reactions of alkynes with secondary amines, which selectively give access to allylic amines with E configuration of the alkene unit, are achieved in the presence of titanium catalysts. Successful reactions of symmetrically substituted diaryl‐ and dialkylalkynes as...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kaper, Tobias, Fischer, Malte, Thye, Hermann, Geik, Dennis, Schmidtmann, Marc, Beckhaus, Ruediger, Doye, Sven
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8248392/ https://www.ncbi.nlm.nih.gov/pubmed/33481309 http://dx.doi.org/10.1002/chem.202100238

Ejemplares similares

Intermolecular Hydroaminoalkylation of Propadiene
por: Kaper, Tobias, et al.
Publicado: (2020)

Titanium‐Catalyzed Intermolecular Hydroaminoalkylation of Alkenes with Tertiary Amines
por: Geik, Dennis, et al.
Publicado: (2021)

Stereoselective Synthesis of Tertiary Allylic Amines by Titanium‐Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines
por: Kaper, Tobias, et al.
Publicado: (2022)

Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
por: Rosien, Michael, et al.
Publicado: (2020)

Linear Hydroaminoalkylation Products from Alkyl‐Substituted Alkenes
por: Warsitz, Michael, et al.
Publicado: (2020)

Ni-catalyzed hydroaminoalkylation of alkynes with amines
por: Yao, Wei-Wei, et al.
Publicado: (2021)

Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines
por: Nako, Adi E., et al.
Publicado: (2016)

Selective propargylic C(sp(3))–H activation of methyl-substituted alkynes versus [2 + 2] cycloaddition at a titanium imido template
por: Fischer, Malte, et al.
Publicado: (2021)

Crystal structure of the η(4)-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-pentamethylcyclopentadienyl)titanium(IV)
por: Fischer, Malte, et al.
Publicado: (2018)

Crystal structure of the formal 20 electron zirconocene pentafulvene complex Cp(2)Zr(η(5),η(1)-adamantylidenepentafulvene):toluene:n-hexane = 1:0.125:0.125
por: Fischer, Malte, et al.
Publicado: (2017)

Tantalum ureate complexes for photocatalytic hydroaminoalkylation
por: Hao, Han, et al.
Publicado: (2023)

α‐Amidoaldehydes as Substrates in Rhodium‐Catalyzed Intermolecular Alkyne Hydroacylation: The Synthesis of α‐Amidoketones
por: Pal, Ritashree, et al.
Publicado: (2020)

Photocatalytic Hydroaminoalkylation of Styrenes with Unprotected Primary Alkylamines
por: Askey, Hannah E., et al.
Publicado: (2021)

Crystal structures of 2,3,8,9,14,15-hexamethyl-5,6,11,12,17,18-hexaazatrinaphthylene and 2,3,8,9,14,15-hexaphenyl-5,6,11,12,17,18-hexazatrinaphthylene dichloromethane disolvate
por: Fangmann, Pia, et al.
Publicado: (2018)

Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes
por: Veenboer, Richard M. P., et al.
Publicado: (2015)

Difunctionalization of Alkenes and Alkynes via Intermolecular Radical and Nucleophilic Additions
por: Yao, Hongjun, et al.
Publicado: (2020)

Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
por: Nguyen, Theresa H, et al.
Publicado: (2014)

Meeting the Challenge of Intermolecular Gold(I)-Catalyzed Cycloadditions of Alkynes and Allenes
por: Muratore, Michael E, et al.
Publicado: (2014)

Ruthenium-catalyzed intermolecular alkene–alkyne couplings in biologically relevant media
por: Gutiérrez-González, Alejandro, et al.
Publicado: (2023)

Anti-Markovnikov Intermolecular Hydroamination of Alkenes and Alkynes: A Mechanistic View
por: Escorihuela, Jorge, et al.
Publicado: (2023)

Crystal structures of titanium–aluminium and –gallium complexes bearing two μ(2)-CH(3) units
por: Oswald, Tim, et al.
Publicado: (2017)

Crystal structures of the Lewis acid–base adducts {[(C(6)H(11))(2)N](3)Ti–LB}(+)[MeB(C(6)F(5))(3)](−)·1.5C(7)H(8); LB = (C(6)H(5))(3)PO (1), p-F—C(6)H(4)CN (2)
por: Fitschen, Kerstin, et al.
Publicado: (2022)

Stereoretentive and regioselective selenium-catalyzed intermolecular propargylic C–H amination of alkynes
por: Maloney, T. Parker, et al.
Publicado: (2022)

Azine-N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
por: Moseley, Daniel F., et al.
Publicado: (2021)

Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
por: Wang, Tao, et al.
Publicado: (2019)

Tetrakis(dicyclohexylamido)zirconium(IV)
por: Frerichs, Nils, et al.
Publicado: (2020)

Regio‐, Diastereo‐, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis
por: Zheng, Jun, et al.
Publicado: (2022)

Electrochemical Hydroboration of Alkynes
por: Aelterman, Maude, et al.
Publicado: (2021)

Palladium(II) Complexes with N-Phosphanyl-N-heterocyclic Carbenes as Catalysts for Intermolecular Alkyne Hydroaminations
por: Franco, Dario, et al.
Publicado: (2018)

Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
por: Zhan, Yi-Zhou, et al.
Publicado: (2021)

Formation of Ruthenium Carbenes by gem-Hydrogen Transfer to Internal Alkynes: Implications for Alkyne trans-Hydrogenation
por: Leutzsch, Markus, et al.
Publicado: (2015)

Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions
por: Svatunek, Dennis, et al.
Publicado: (2018)

Hydrofluorination of Alkynes Catalysed by Gold Bifluorides
por: Nahra, Fady, et al.
Publicado: (2015)

Silver‐Catalyzed Stereoselective Aminosulfonylation of Alkynes
por: Ning, Yongquan, et al.
Publicado: (2017)

Glycerol as Precursor of Organoselanyl and Organotellanyl Alkynes
por: Lenardão, Eder J., et al.
Publicado: (2017)

Conditional Copper‐Catalyzed Azide–Alkyne Cycloaddition by Catalyst Encapsulation
por: Brevé, Tobias G., et al.
Publicado: (2020)

An Anionic Dinuclear Ruthenium Dihydrogen Complex of Relevance for Alkyne gem‐Hydrogenation
por: Biberger, Tobias, et al.
Publicado: (2022)

Grubbs Metathesis Enabled by a Light‐Driven gem‐Hydrogenation of Internal Alkynes
por: Biberger, Tobias, et al.
Publicado: (2020)

(Carbazol-9-ido-κN)dichlorido(η(5):η(1)-2,3,4,5-tetramethylpentafulvene)tantalum(V)
por: de Graaff, Simon, et al.
Publicado: (2022)

SmI(2)-Catalyzed Intermolecular Coupling of Cyclopropyl Ketones and Alkynes: A Link between Ketone Conformation and Reactivity
por: Agasti, Soumitra, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_lcerdba4vam8jbra6irvpg8vfv