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Palladium‐Catalyzed Cascade to Benzoxepins by Using Vinyl‐Substituted Donor–Acceptor Cyclopropanes

A palladium‐catalyzed intermolecular cascade (4+3) cyclocondensation of salicylaldehydes and vinylcyclopropanes is reported. A key feature of the reaction is the use of a phosphonate group as an acceptor moiety on the cyclopropane, exploiting its propensity to undergo olefination with aldehydes. Sub...

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Detalles Bibliográficos
Autores principales:	Faltracco, Matteo, van de Vrande, Koen N. A., Dijkstra, Martijn, Saya, Jordy M., Hamlin, Trevor A., Ruijter, Eelco
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251625/ https://www.ncbi.nlm.nih.gov/pubmed/33822456 http://dx.doi.org/10.1002/anie.202102862

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