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The Synthesis and Characterisation of a Molecular Sea‐Serpent: Studies of a {Cr(24)Cu(7)} Chain
A finite chain of thirty‐one paramagnetic centers is reported, synthesized by reaction of hydrated chromium fluoride, copper carbonate and pivalic acid in the presence of 1,4,7,10‐tetrazacyclododecane (cyclen). Magnetic studies show predominantly anti‐ferromagnetic exchange leading to a high density...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251705/ https://www.ncbi.nlm.nih.gov/pubmed/33576165 http://dx.doi.org/10.1002/anie.202015731 |