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Wavelength‐Gated Photochemical Synthesis of Phenalene Diimides

Herein, we pioneer a wavelength‐gated synthesis route to phenalene diimides. Consecutive Diels–Alder reactions of methylisophthalaldehydes and maleimides afford hexahydro‐phenalene‐1,6‐diol diimides via 5‐formyl‐hexahydro‐benzo[f]isoindoles as the intermediate. Both photoreactions are efficient (82–...

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Detalles Bibliográficos
Autores principales: Feist, Florian, Walden, Sarah L., Alves, Jessica, Kunz, Susanna V., Micallef, Aaron S., Brock, Aidan J., McMurtrie, John C., Weil, Tanja, Blinco, James P., Barner‐Kowollik, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251713/
https://www.ncbi.nlm.nih.gov/pubmed/33571392
http://dx.doi.org/10.1002/anie.202016632