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Highly Coordinated Heteronuclear Calcium–Iron Carbonyl Cation Complexes [CaFe(CO)(n)](+) (n=5–12) with d−d Bonding

Heteronuclear calcium–iron carbonyl cation complexes in the form of [CaFe(CO)(n)](+) (n=5–12) are produced in the gas phase. Infrared photodissociation spectroscopy in conjunction with quantum chemical calculations confirm that the n=10 complex is the coordination saturated ion where a Fe(CO)(4) fra...

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Detalles Bibliográficos
Autores principales:	Jin, Xiaoyang, Bai, Yuna, Zhou, Yangyu, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251804/ https://www.ncbi.nlm.nih.gov/pubmed/33826215 http://dx.doi.org/10.1002/anie.202103267

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