Water‐Assisted Concerted Proton‐Electron Transfer at Co(II)‐Aquo Sites in Polyoxotungstates With Photogenerated Ru(III)(bpy)(3) (3+) Oxidant

The cobalt substituted polyoxotungstate [Co(6)(H(2)O)(2)(α‐B‐PW(9)O(34))(2)(PW(6)O(26))](17−) (Co6) displays fast electron transfer (ET) kinetics to photogenerated Ru(III)(bpy)(3) (3+), 4 to 5 orders of magnitude faster than the corresponding ET observed for cobalt oxide nanoparticles. Mechanistic e...

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Detalles Bibliográficos
Autores principales: Rigodanza, Francesco, Marino, Nadia, Bonetto, Alessandro, Marcomini, Antonio, Bonchio, Marcella, Natali, Mirco, Sartorel, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251842/
https://www.ncbi.nlm.nih.gov/pubmed/33851772
http://dx.doi.org/10.1002/cphc.202100190

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251842/
https://www.ncbi.nlm.nih.gov/pubmed/33851772
http://dx.doi.org/10.1002/cphc.202100190

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