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Enantioselective Alkoxycyclization of 1,6‐Enynes with Gold(I)‐Cavitands: Total Synthesis of Mafaicheenamine C

Chiral gold(I)‐cavitand complexes have been developed for the enantioselective alkoxycyclization of 1,6‐enynes. This enantioselective cyclization has been applied for the first total synthesis of carbazole alkaloid (+)‐mafaicheenamine C and its enantiomer, establishing its configuration as R. The ca...

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Detalles Bibliográficos
Autores principales:	Martín‐Torres, Inmaculada, Ogalla, Gala, Yang, Jin‐Ming, Rinaldi, Antonia, Echavarren, Antonio M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251978/ https://www.ncbi.nlm.nih.gov/pubmed/33576560 http://dx.doi.org/10.1002/anie.202017035

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