Electrochemical Dehydrogenative C(sp(2))−H Amination

A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intra...

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Detalles Bibliográficos
Autores principales: Puthanveedu, Mahesh, Khamraev, Vladislav, Brieger, Lukas, Strohmann, Carsten, Antonchick, Andrey P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251997/
https://www.ncbi.nlm.nih.gov/pubmed/33931904
http://dx.doi.org/10.1002/chem.202100960
Descripción
Sumario:A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup.

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