Electrochemical Dehydrogenative C(sp(2))−H Amination

A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intra...

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Detalles Bibliográficos
Autores principales: Puthanveedu, Mahesh, Khamraev, Vladislav, Brieger, Lukas, Strohmann, Carsten, Antonchick, Andrey P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251997/
https://www.ncbi.nlm.nih.gov/pubmed/33931904
http://dx.doi.org/10.1002/chem.202100960
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author Puthanveedu, Mahesh
Khamraev, Vladislav
Brieger, Lukas
Strohmann, Carsten
Antonchick, Andrey P.
author_facet Puthanveedu, Mahesh
Khamraev, Vladislav
Brieger, Lukas
Strohmann, Carsten
Antonchick, Andrey P.
author_sort Puthanveedu, Mahesh
collection PubMed
description A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup.
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spelling pubmed-82519972021-07-07 Electrochemical Dehydrogenative C(sp(2))−H Amination Puthanveedu, Mahesh Khamraev, Vladislav Brieger, Lukas Strohmann, Carsten Antonchick, Andrey P. Chemistry Communications A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup. John Wiley and Sons Inc. 2021-05-01 2021-05-26 /pmc/articles/PMC8251997/ /pubmed/33931904 http://dx.doi.org/10.1002/chem.202100960 Text en © 2021 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Puthanveedu, Mahesh
Khamraev, Vladislav
Brieger, Lukas
Strohmann, Carsten
Antonchick, Andrey P.
Electrochemical Dehydrogenative C(sp(2))−H Amination
title Electrochemical Dehydrogenative C(sp(2))−H Amination
title_full Electrochemical Dehydrogenative C(sp(2))−H Amination
title_fullStr Electrochemical Dehydrogenative C(sp(2))−H Amination
title_full_unstemmed Electrochemical Dehydrogenative C(sp(2))−H Amination
title_short Electrochemical Dehydrogenative C(sp(2))−H Amination
title_sort electrochemical dehydrogenative c(sp(2))−h amination
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251997/
https://www.ncbi.nlm.nih.gov/pubmed/33931904
http://dx.doi.org/10.1002/chem.202100960
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AT khamraevvladislav electrochemicaldehydrogenativecsp2hamination
AT briegerlukas electrochemicaldehydrogenativecsp2hamination
AT strohmanncarsten electrochemicaldehydrogenativecsp2hamination
AT antonchickandreyp electrochemicaldehydrogenativecsp2hamination

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