Cargando…

Electrochemical Dehydrogenative C(sp(2))−H Amination

A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intra...

Descripción completa

Detalles Bibliográficos
Autores principales:	Puthanveedu, Mahesh, Khamraev, Vladislav, Brieger, Lukas, Strohmann, Carsten, Antonchick, Andrey P.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251997/ https://www.ncbi.nlm.nih.gov/pubmed/33931904 http://dx.doi.org/10.1002/chem.202100960

Ejemplares similares

Stereoselective Synthesis of Cyclobutanes by Contraction of Pyrrolidines
por: Hui, Chunngai, et al.
Publicado: (2021)

Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
por: Scheel, Rebecca, et al.
Publicado: (2020)

Dynamic Catalytic Highly Enantioselective 1,3‐Dipolar Cycloadditions
por: Yildirim, Okan, et al.
Publicado: (2021)

Crystal structure of dicarbonyl[μ(2)-methylenebis(diphenylphosphane)-κ(2) P:P′][μ(2)-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)–dichloromethane–toluene (1/1/2), [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(2,4,5-C(6)H(2)Me(3))=CH)Pt(PPh(3))]
por: Brieger, Lukas, et al.
Publicado: (2019)

Crystal structure of {μ(2)-1,2-bis[(4-methylphenylsulfanyl]-3-oxoprop-1-ene-1,3-diyl-1:2κ(2) C (3):C (1)}dicarbonyl-1κ(2) C-[μ(2)-methylenebis(diphenylphosphane)-1:2κ(2) P:P′](triphenylphosphane-2κP)ironplatinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
por: Mohamed, Ahmed Said, et al.
Publicado: (2020)

Electrochemical Dehydrogenation Pathways of Amines to Nitriles on NiOOH
por: Bender, Michael T., et al.
Publicado: (2022)

THF‐solvated Heavy Alkali Metal Benzyl Compounds (Na, Rb, Cs): Defined Deprotonation Reagents for Alkali Metal Mediation Chemistry
por: Brieger, Lukas, et al.
Publicado: (2021)

Crystal structure and Hirshfeld surface analysis of (S)-N-methyl-1-phenylethan-1-aminium chloride
por: Kirchhoff, Jan-Lukas, et al.
Publicado: (2022)

Electrochemical Synthesis of Carbazoles by Dehydrogenative Coupling Reaction
por: Kehl, Anton, et al.
Publicado: (2020)

Electrochemical Dehydrogenative Acetalization Protection of Alcohols with Tetrahydrofuran
por: Huang, Raolin, et al.
Publicado: (2021)

Copper-catalyzed dehydrogenative γ-C(sp(3))-H amination of saturated ketones for synthesis of polysubstituted anilines
por: Hu, Rong, et al.
Publicado: (2019)

Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct
por: Brieger, Lukas, et al.
Publicado: (2018)

Electrochemical Dehydrogenative C−H Aminomethylation of Imidazopyridines and Related Heterocycles
por: Huang, Raolin, et al.
Publicado: (2022)

Cascade aza-Wittig/6π-Electrocyclization in the Synthesis of 1,6-Dihydropyridines
por: Polychronidou, Vasiliki, et al.
Publicado: (2021)

Author Correction: Copper-catalyzed dehydrogenative γ-C(sp(3))-H amination of saturated ketones for synthesis of polysubstituted anilines
por: Hu, Rong, et al.
Publicado: (2021)

Crystal structure of N,N,N′,N′-tetramethylethanediamine
por: Schrimpf, Tobias, et al.
Publicado: (2022)

Copper-Mediated Dehydrogenative C(sp(3))–H Borylation of Alkanes
por: Sang, Ruocheng, et al.
Publicado: (2023)

Cross-dehydrogenative coupling and oxidative-amination reactions of ethers and alcohols with aromatics and heteroaromatics
por: Lakshman, Mahesh K., et al.
Publicado: (2017)

Practical Catalytic Cleavage of C(sp(3))−C(sp(3)) Bonds in Amines
por: Li, Wu, et al.
Publicado: (2019)

Crystal structures of [Li(7)(i-PrO)(3)(C(4)H(10)NO)(3)](2)O and [Na(i-PrOH)(2)(C(8)H(18)NO(2))](2)
por: Scheel, Rebecca, et al.
Publicado: (2020)

Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp(3) carbons
por: Wu, Xuesong, et al.
Publicado: (2015)

Dehydrogenative C–H Phenochalcogenazination
por: Cremer, Christopher, et al.
Publicado: (2021)

Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds
por: Wu, Xuesong, et al.
Publicado: (2015)

Enantioselective Synthesis of Five-Membered-Ring Atropisomers with a Chiral Rh(III) Complex
por: Shaaban, Saad, et al.
Publicado: (2020)

Aminopotassiation by Mixed Potassium/Lithium Amides: A Synthetic Path to Difficult to Access Phenethylamine Derivates
por: Seymen, Andreas, et al.
Publicado: (2020)

Dehydrogenation of Amine–Boranes Using p‐Block Compounds
por: Boom, Devin H. A., et al.
Publicado: (2019)

Synthesis of N-aryl amines enabled by photocatalytic dehydrogenation
por: Kim, Jungwon, et al.
Publicado: (2020)

[1+1+1] Cyclotrimerization for the Synthesis of Cyclopropanes
por: Manna, Srimanta, et al.
Publicado: (2016)

Transition-metal-free C(sp(3))–H/C(sp(3))–H dehydrogenative coupling of saturated heterocycles with N-benzyl imines
por: Liu, Zhengfen, et al.
Publicado: (2020)

Efficient Amination of Activated and Non‐Activated C(sp(3))−H Bonds with a Simple Iron–Phenanthroline Catalyst
por: Jarrige, Lucie, et al.
Publicado: (2021)

Synthesis of 2-oxindoles via 'transition-metal-free' intramolecular dehydrogenative coupling (IDC) of sp(2) C–H and sp(3) C–H bonds
por: Kumar, Nivesh, et al.
Publicado: (2016)

Rh(III)‐Catalyzed C−H Activation of Aryl Hydroxamates for the Synthesis of Isoindolinones
por: Shaaban, Saad, et al.
Publicado: (2020)

Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines
por: Lane, Elizabeth M., et al.
Publicado: (2018)

Fragile intermediate identification and reactivity elucidation in electrochemical oxidative α-C(sp(3))–H functionalization of tertiary amines
por: Liang, Kailun, et al.
Publicado: (2023)

Dehydrogenative Anodic C−C Coupling of Phenols Bearing Electron‐Withdrawing Groups
por: Röckl, Johannes L., et al.
Publicado: (2019)

Metal-free oxidative cross-dehydrogenative coupling of quinones with benzylic C(sp(3))–H bonds
por: Dong, Yu, et al.
Publicado: (2019)

Electrochemical C–H oxygenation and alcohol dehydrogenation involving Fe-oxo species using water as the oxygen source
por: Das, Amit, et al.
Publicado: (2019)

Consecutive β,β′‐Selective C(sp(3))−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C(6)F(5))(3)
por: Fang, Huaquan, et al.
Publicado: (2021)

Palladium‐Catalyzed PIDA‐Mediated δ‐C(sp(3))−H Acetoxylation of Amino Acid Derivatives: Overriding Competitive Intramolecular Amination
por: Martínez‐Mingo, Mario, et al.
Publicado: (2022)

Towards Substrate–Reagent Interaction of Lochmann–Schlosser Bases in THF: Bridging THF Hides Potential Reaction Site of a Chiral Superbase
por: Brieger, Lukas, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_u0332kdtr0bdq61tvh794q93uc