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Photoredox Catalytic Pentafluorosulfanylative Domino Cyclization of α‐Substituted Alkenes to Oxaheterocycles by Using SF(6)

Virtually inert sulfur hexafluoride becomes a precious pentafluorosulfanylation agent, if properly activated by photoredox catalysis, to access α‐fluoro and α‐alkoxy SF(5)‐compounds. This advanced protocol converts SF(6) in the presence of alkynols as bifunctional C−C‐ and C−O‐bond forming reagents...

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Detalles Bibliográficos
Autores principales: Rombach, David, Birenheide, Bernhard, Wagenknecht, Hans‐Achim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252034/
https://www.ncbi.nlm.nih.gov/pubmed/33831262
http://dx.doi.org/10.1002/chem.202100767

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