Diphosphanylmetallocenes of Main‐Group Elements

Several 1,1′‐diphosphanyl‐substituted metallocenes of magnesium (magnesocenes) were synthesized, structurally characterized, and their reactivity and coordination chemistry were investigated. Transmetalation of these magnesocenes gives access to group 14 metallocenes (tetrelocenes), as well as to gr...

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Autores principales: Müller, Carsten, Warken, Joshua, Huch, Volker, Morgenstern, Bernd, Bischoff, Inga‐Alexandra, Zimmer, Michael, Schäfer, André
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252418/
https://www.ncbi.nlm.nih.gov/pubmed/33411379
http://dx.doi.org/10.1002/chem.202005198
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author Müller, Carsten
Warken, Joshua
Huch, Volker
Morgenstern, Bernd
Bischoff, Inga‐Alexandra
Zimmer, Michael
Schäfer, André
author_facet Müller, Carsten
Warken, Joshua
Huch, Volker
Morgenstern, Bernd
Bischoff, Inga‐Alexandra
Zimmer, Michael
Schäfer, André
author_sort Müller, Carsten
collection PubMed
description Several 1,1′‐diphosphanyl‐substituted metallocenes of magnesium (magnesocenes) were synthesized, structurally characterized, and their reactivity and coordination chemistry were investigated. Transmetalation of these magnesocenes gives access to group 14 metallocenes (tetrelocenes), as well as to group 15 stibonocenes. These s‐ and p‐block metallocenes represent a novel class of bis(phosphanyl) ligands, exhibiting Lewis‐amphiphilic character. Their coordination chemistry towards different transition‐metal and main‐group fragments was investigated and different complexes are presented.
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spelling pubmed-82524182021-07-07 Diphosphanylmetallocenes of Main‐Group Elements Müller, Carsten Warken, Joshua Huch, Volker Morgenstern, Bernd Bischoff, Inga‐Alexandra Zimmer, Michael Schäfer, André Chemistry Full Papers Several 1,1′‐diphosphanyl‐substituted metallocenes of magnesium (magnesocenes) were synthesized, structurally characterized, and their reactivity and coordination chemistry were investigated. Transmetalation of these magnesocenes gives access to group 14 metallocenes (tetrelocenes), as well as to group 15 stibonocenes. These s‐ and p‐block metallocenes represent a novel class of bis(phosphanyl) ligands, exhibiting Lewis‐amphiphilic character. Their coordination chemistry towards different transition‐metal and main‐group fragments was investigated and different complexes are presented. John Wiley and Sons Inc. 2021-03-08 2021-04-12 /pmc/articles/PMC8252418/ /pubmed/33411379 http://dx.doi.org/10.1002/chem.202005198 Text en © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Müller, Carsten
Warken, Joshua
Huch, Volker
Morgenstern, Bernd
Bischoff, Inga‐Alexandra
Zimmer, Michael
Schäfer, André
Diphosphanylmetallocenes of Main‐Group Elements
title Diphosphanylmetallocenes of Main‐Group Elements
title_full Diphosphanylmetallocenes of Main‐Group Elements
title_fullStr Diphosphanylmetallocenes of Main‐Group Elements
title_full_unstemmed Diphosphanylmetallocenes of Main‐Group Elements
title_short Diphosphanylmetallocenes of Main‐Group Elements
title_sort diphosphanylmetallocenes of main‐group elements
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252418/
https://www.ncbi.nlm.nih.gov/pubmed/33411379
http://dx.doi.org/10.1002/chem.202005198
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