Cargando…
Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion
Bis(1‐(4‐tolyl)‐carboran‐2‐yl)‐(4‐tolyl)‐borane [(1‐(4‐MeC(6)H(4))‐closo‐1,2‐C(2)B(10)H(10)‐2‐)(2)(4‐MeC(6)H(4))B] (1), a new bis(o‐carboranyl)‐(R)‐borane was synthesised by lithiation of the o‐carboranyl precursor and subsequent salt metathesis reaction with (4‐tolyl)BBr(2). Cyclic voltammetry expe...
Autores principales: | Krebs, Johannes, Haehnel, Martin, Krummenacher, Ivo, Friedrich, Alexandra, Braunschweig, Holger, Finze, Maik, Ji, Lei, Marder, Todd B. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252506/ https://www.ncbi.nlm.nih.gov/pubmed/33769625 http://dx.doi.org/10.1002/chem.202100938 |
Ejemplares similares
-
An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers
por: Rauch, Florian, et al.
Publicado: (2020) -
Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene
por: Bischof, Tobias, et al.
Publicado: (2022) -
Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives
por: Krebs, Johannes, et al.
Publicado: (2022) -
Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors
por: Rauch, Florian, et al.
Publicado: (2020) -
Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence
por: He, Jiang, et al.
Publicado: (2021)