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Photoinduced Electron vs. Concerted Proton Electron Transfer Pathways in Sn(IV) (l‐Tryptophanato)(2) Porphyrin Conjugates
Aromatic amino acids such as l‐tyrosine and l‐tryptophan are deployed in natural systems to mediate electron transfer (ET) reactions. While tyrosine oxidation is always coupled to deprotonation (proton‐coupled electron‐transfer, PCET), both ET‐only and PCET pathways can occur in the case of the tryp...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252543/ https://www.ncbi.nlm.nih.gov/pubmed/33780047 http://dx.doi.org/10.1002/chem.202005487 |