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A Stable Homoleptic Divinyl Tetrelene Series

The synthesis of the new bulky vinyllithium reagent ((Me)IPr=CH)Li, ((Me)IPr=[(MeCNDipp)(2)C]; Dipp=2,6‐iPr(2)C(6)H(3)) is reported. This vinyllithium precursor was found to act as a general source of the anionic 2σ, 2π‐electron donor ligand [(Me)IPr=CH](−). Furthermore, a high‐yielding route to the...

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Detalles Bibliográficos
Autores principales:	Roy, Matthew M. D., Baird, Samuel R., Dornsiepen, Eike, Paul, Lucas A., Miao, Linkun, Ferguson, Michael J., Zhou, Yuqiao, Siewert, Inke, Rivard, Eric
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252546/ https://www.ncbi.nlm.nih.gov/pubmed/33848023 http://dx.doi.org/10.1002/chem.202100969

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