Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives

The propensity of the new, phenylphosphonate‐stabilized polyoxotungstate [(C(6)H(5)P(V)O)(2)P(4)W(24)O(92)](16−) to act as a precursor for new 3d metal‐functionalized polyanions has been investigated. Reactions with Mn(II) and Cu(II) induce the formation of the previously unknown polyoxotungstate ar...

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Autores principales: Iftikhar, Tuba, Izarova, Natalya V., van Leusen, Jan, Kögerler, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252624/
https://www.ncbi.nlm.nih.gov/pubmed/33826185
http://dx.doi.org/10.1002/chem.202004894
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author Iftikhar, Tuba
Izarova, Natalya V.
van Leusen, Jan
Kögerler, Paul
author_facet Iftikhar, Tuba
Izarova, Natalya V.
van Leusen, Jan
Kögerler, Paul
author_sort Iftikhar, Tuba
collection PubMed
description The propensity of the new, phenylphosphonate‐stabilized polyoxotungstate [(C(6)H(5)P(V)O)(2)P(4)W(24)O(92)](16−) to act as a precursor for new 3d metal‐functionalized polyanions has been investigated. Reactions with Mn(II) and Cu(II) induce the formation of the previously unknown polyoxotungstate archetype {P(4)W(27)}, isolated as salts of the polyanions [Na⊂{Mn(II)(H(2)O)}{WO(H(2)O)}P(4)W(26)O(98)](13−) (1) and [K⊂{Cu(II)(H(2)O)}{W(OH)(H(2)O)}P(4)W(27)O(99)](14−) (2), which were characterized in the solid state (single‐crystal X‐ray diffraction, elemental and TG analyses, IR spectroscopy, SQUID magnetometry) and in aqueous solution (UV/Vis spectroscopy, cyclic voltammetry).
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spelling pubmed-82526242021-07-09 Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives Iftikhar, Tuba Izarova, Natalya V. van Leusen, Jan Kögerler, Paul Chemistry Full Papers The propensity of the new, phenylphosphonate‐stabilized polyoxotungstate [(C(6)H(5)P(V)O)(2)P(4)W(24)O(92)](16−) to act as a precursor for new 3d metal‐functionalized polyanions has been investigated. Reactions with Mn(II) and Cu(II) induce the formation of the previously unknown polyoxotungstate archetype {P(4)W(27)}, isolated as salts of the polyanions [Na⊂{Mn(II)(H(2)O)}{WO(H(2)O)}P(4)W(26)O(98)](13−) (1) and [K⊂{Cu(II)(H(2)O)}{W(OH)(H(2)O)}P(4)W(27)O(99)](14−) (2), which were characterized in the solid state (single‐crystal X‐ray diffraction, elemental and TG analyses, IR spectroscopy, SQUID magnetometry) and in aqueous solution (UV/Vis spectroscopy, cyclic voltammetry). John Wiley and Sons Inc. 2021-05-13 2021-06-10 /pmc/articles/PMC8252624/ /pubmed/33826185 http://dx.doi.org/10.1002/chem.202004894 Text en © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Iftikhar, Tuba
Izarova, Natalya V.
van Leusen, Jan
Kögerler, Paul
Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives
title Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives
title_full Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives
title_fullStr Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives
title_full_unstemmed Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives
title_short Polyoxotungstate Archetype {P(4)W(27)} and its 3d Derivatives
title_sort polyoxotungstate archetype {p(4)w(27)} and its 3d derivatives
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252624/
https://www.ncbi.nlm.nih.gov/pubmed/33826185
http://dx.doi.org/10.1002/chem.202004894
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AT vanleusenjan polyoxotungstatearchetypep4w27andits3dderivatives
AT kogerlerpaul polyoxotungstatearchetypep4w27andits3dderivatives

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