Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid

A facile synthesis and isolation of pristine silicon tetrakis(trifluoromethanesulfonate), Si(OTf)(4), is reported, acting as the first neutral silicon‐based Lewis superacid suitable towards soft and hard Lewis bases. Its OTf groups have a dual function: they are excellent leaving groups and modulate...

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Detalles Bibliográficos
Autores principales: Hermannsdorfer, André, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252640/
https://www.ncbi.nlm.nih.gov/pubmed/33826216
http://dx.doi.org/10.1002/anie.202103414

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252640/
https://www.ncbi.nlm.nih.gov/pubmed/33826216
http://dx.doi.org/10.1002/anie.202103414

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