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Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid
A facile synthesis and isolation of pristine silicon tetrakis(trifluoromethanesulfonate), Si(OTf)(4), is reported, acting as the first neutral silicon‐based Lewis superacid suitable towards soft and hard Lewis bases. Its OTf groups have a dual function: they are excellent leaving groups and modulate...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252640/ https://www.ncbi.nlm.nih.gov/pubmed/33826216 http://dx.doi.org/10.1002/anie.202103414 |