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Zeolite‐Stabilized Di‐ and Tetranuclear Molybdenum Sulfide Clusters Form Stable Catalytic Hydrogenation Sites

Supercages of faujasite (FAU)‐type zeolites serve as a robust scaffold for stabilizing dinuclear (Mo(2)S(4)) and tetranuclear (Mo(4)S(4)) molybdenum sulfide clusters. The FAU‐encaged Mo(4)S(4) clusters have a distorted cubane structure similar to the FeMo‐cofactor in nitrogenase. Both clusters posse...

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Detalles Bibliográficos
Autores principales:	Weindl, Roland, Khare, Rachit, Kovarik, Libor, Jentys, Andreas, Reuter, Karsten, Shi, Hui, Lercher, Johannes A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252740/ https://www.ncbi.nlm.nih.gov/pubmed/33576131 http://dx.doi.org/10.1002/anie.202015769

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