Ambiphilic Al−Cu Bonding

Copper‐alumanyl complexes, [LCu‐Al(SiN(Dipp))], where L=carbene=NHC(iPr) (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and (Me2)CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al−Cu bonds, have been prepared. Divergent reactivity observed with carbodii...

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Detalles Bibliográficos
Autores principales: Liu, Han‐Ying, Schwamm, Ryan J., Hill, Michael S., Mahon, Mary F., McMullin, Claire L., Rajabi, Nasir A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252794/
https://www.ncbi.nlm.nih.gov/pubmed/33899319
http://dx.doi.org/10.1002/anie.202104658
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author Liu, Han‐Ying
Schwamm, Ryan J.
Hill, Michael S.
Mahon, Mary F.
McMullin, Claire L.
Rajabi, Nasir A.
author_facet Liu, Han‐Ying
Schwamm, Ryan J.
Hill, Michael S.
Mahon, Mary F.
McMullin, Claire L.
Rajabi, Nasir A.
author_sort Liu, Han‐Ying
collection PubMed
description Copper‐alumanyl complexes, [LCu‐Al(SiN(Dipp))], where L=carbene=NHC(iPr) (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and (Me2)CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al−Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO(2) implies an ambiphilicity in the Cu–Al interaction that is dependent on the identity of the carbene co‐ligand.
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spelling pubmed-82527942021-07-12 Ambiphilic Al−Cu Bonding Liu, Han‐Ying Schwamm, Ryan J. Hill, Michael S. Mahon, Mary F. McMullin, Claire L. Rajabi, Nasir A. Angew Chem Int Ed Engl Communications Copper‐alumanyl complexes, [LCu‐Al(SiN(Dipp))], where L=carbene=NHC(iPr) (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and (Me2)CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al−Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO(2) implies an ambiphilicity in the Cu–Al interaction that is dependent on the identity of the carbene co‐ligand. John Wiley and Sons Inc. 2021-05-20 2021-06-21 /pmc/articles/PMC8252794/ /pubmed/33899319 http://dx.doi.org/10.1002/anie.202104658 Text en © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Liu, Han‐Ying
Schwamm, Ryan J.
Hill, Michael S.
Mahon, Mary F.
McMullin, Claire L.
Rajabi, Nasir A.
Ambiphilic Al−Cu Bonding
title Ambiphilic Al−Cu Bonding
title_full Ambiphilic Al−Cu Bonding
title_fullStr Ambiphilic Al−Cu Bonding
title_full_unstemmed Ambiphilic Al−Cu Bonding
title_short Ambiphilic Al−Cu Bonding
title_sort ambiphilic al−cu bonding
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252794/
https://www.ncbi.nlm.nih.gov/pubmed/33899319
http://dx.doi.org/10.1002/anie.202104658
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AT hillmichaels ambiphilicalcubonding
AT mahonmaryf ambiphilicalcubonding
AT mcmullinclairel ambiphilicalcubonding
AT rajabinasira ambiphilicalcubonding

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