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Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network
Stretchable ionic skins are intriguing in mimicking the versatile sensations of natural skins. However, for their applications in advanced electronics, good elastic recovery, self-healing, and more importantly, skin-like nonlinear mechanoresponse (strain-stiffening) are essential but can be rarely m...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8253733/ https://www.ncbi.nlm.nih.gov/pubmed/34215738 http://dx.doi.org/10.1038/s41467-021-24382-4 |
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author | Zhang, Wei Wu, Baohu Sun, Shengtong Wu, Peiyi |
author_facet | Zhang, Wei Wu, Baohu Sun, Shengtong Wu, Peiyi |
author_sort | Zhang, Wei |
collection | PubMed |
description | Stretchable ionic skins are intriguing in mimicking the versatile sensations of natural skins. However, for their applications in advanced electronics, good elastic recovery, self-healing, and more importantly, skin-like nonlinear mechanoresponse (strain-stiffening) are essential but can be rarely met in one material. Here we demonstrate a robust proton-conductive ionic skin design via introducing an entropy-driven supramolecular zwitterionic reorganizable network to the hydrogen-bonded polycarboxylic acid network. The design allows two dynamic networks with distinct interacting strength to sequentially debond with stretch, and the conflict among elasticity, self-healing, and strain-stiffening can be thus defeated. The representative polyacrylic acid/betaine elastomer exhibits high stretchability (1600% elongation), immense strain-stiffening (24-fold modulus enhancement), ~100% self-healing, excellent elasticity (97.9 ± 1.1% recovery ratio, <14% hysteresis), high transparency (99.7 ± 0.1%), moisture-preserving, anti-freezing (elastic at −40 °C), water reprocessibility, as well as easy-to-peel adhesion. The combined advantages make the present ionic elastomer very promising in wearable iontronic sensors for human-machine interfacing. |
format | Online Article Text |
id | pubmed-8253733 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-82537332021-07-20 Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network Zhang, Wei Wu, Baohu Sun, Shengtong Wu, Peiyi Nat Commun Article Stretchable ionic skins are intriguing in mimicking the versatile sensations of natural skins. However, for their applications in advanced electronics, good elastic recovery, self-healing, and more importantly, skin-like nonlinear mechanoresponse (strain-stiffening) are essential but can be rarely met in one material. Here we demonstrate a robust proton-conductive ionic skin design via introducing an entropy-driven supramolecular zwitterionic reorganizable network to the hydrogen-bonded polycarboxylic acid network. The design allows two dynamic networks with distinct interacting strength to sequentially debond with stretch, and the conflict among elasticity, self-healing, and strain-stiffening can be thus defeated. The representative polyacrylic acid/betaine elastomer exhibits high stretchability (1600% elongation), immense strain-stiffening (24-fold modulus enhancement), ~100% self-healing, excellent elasticity (97.9 ± 1.1% recovery ratio, <14% hysteresis), high transparency (99.7 ± 0.1%), moisture-preserving, anti-freezing (elastic at −40 °C), water reprocessibility, as well as easy-to-peel adhesion. The combined advantages make the present ionic elastomer very promising in wearable iontronic sensors for human-machine interfacing. Nature Publishing Group UK 2021-07-02 /pmc/articles/PMC8253733/ /pubmed/34215738 http://dx.doi.org/10.1038/s41467-021-24382-4 Text en © The Author(s) 2021 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Zhang, Wei Wu, Baohu Sun, Shengtong Wu, Peiyi Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
title | Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
title_full | Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
title_fullStr | Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
title_full_unstemmed | Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
title_short | Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
title_sort | skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8253733/ https://www.ncbi.nlm.nih.gov/pubmed/34215738 http://dx.doi.org/10.1038/s41467-021-24382-4 |
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