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Oxalate decarboxylase uses electron hole hopping for catalysis

The hexameric low-pH stress response enzyme oxalate decarboxylase catalyzes the decarboxylation of the oxalate mono-anion in the soil bacterium Bacillus subtilis. A single protein subunit contains two Mn-binding cupin domains, and catalysis depends on Mn(III) at the N-terminal site. The present stud...

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Detalles Bibliográficos
Autores principales: Pastore, Anthony J., Teo, Ruijie D., Montoya, Alvaro, Burg, Matthew J., Twahir, Umar T., Bruner, Steven D., Beratan, David N., Angerhofer, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Society for Biochemistry and Molecular Biology 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8254039/
https://www.ncbi.nlm.nih.gov/pubmed/34097877
http://dx.doi.org/10.1016/j.jbc.2021.100857