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Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation

[Image: see text] Polycyclic aromatic hydrocarbons are a class of persistent organic water pollutants that raise serious concerns owing to their carcinogenicity and other negative impacts on humans and ecosystems. In this study, Bi(2)MoO(6)/reduced graphene oxide (rGO) nanocomposites were designed a...

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Detalles Bibliográficos
Autores principales: Maswanganyi, Shelter, Gusain, Rashi, Kumar, Neeraj, Fosso-Kankeu, Elvis, Waanders, Frans Boudewijn, Ray, Suprakas Sinha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8264845/
https://www.ncbi.nlm.nih.gov/pubmed/34250338
http://dx.doi.org/10.1021/acsomega.1c01296
Descripción
Sumario:[Image: see text] Polycyclic aromatic hydrocarbons are a class of persistent organic water pollutants that raise serious concerns owing to their carcinogenicity and other negative impacts on humans and ecosystems. In this study, Bi(2)MoO(6)/reduced graphene oxide (rGO) nanocomposites were designed and prepared for the adsorption-assisted photodegradation of naphthalene molecules in an aqueous medium. The synthesized Bi(2)MoO(6) nanoplates and Bi(2)MoO(6)/rGO nanocomposites were characterized by X-ray diffraction, Fourier transform infrared, scanning electron microscopy, high-resolution transmission microscopy, X-ray photoelectron spectroscopy, ultraviolet spectroscopy, Brunauer–Emmett–Teller, and photoluminescence measurements. The photodegradation of naphthalene molecules was observed to assess the photocatalytic characteristics of the samples under visible light. The Bi(2)MoO(6)/rGO nanocomposites exhibited significantly improved photocatalytic efficiency compared to pure Bi(2)MoO(6). Among the nanocomposites, those containing 2 wt % rGO showed the best photocatalytic activity. The incorporation of rGO enhanced the visible light absorption and decreased the recombination rate of photogenerated charge carriers. Moreover, a Bi(2)MoO(6)/rGO nanocomposite showed excellent reusability for five cycles.