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Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation

[Image: see text] Polycyclic aromatic hydrocarbons are a class of persistent organic water pollutants that raise serious concerns owing to their carcinogenicity and other negative impacts on humans and ecosystems. In this study, Bi(2)MoO(6)/reduced graphene oxide (rGO) nanocomposites were designed a...

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Autores principales: Maswanganyi, Shelter, Gusain, Rashi, Kumar, Neeraj, Fosso-Kankeu, Elvis, Waanders, Frans Boudewijn, Ray, Suprakas Sinha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8264845/
https://www.ncbi.nlm.nih.gov/pubmed/34250338
http://dx.doi.org/10.1021/acsomega.1c01296
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author Maswanganyi, Shelter
Gusain, Rashi
Kumar, Neeraj
Fosso-Kankeu, Elvis
Waanders, Frans Boudewijn
Ray, Suprakas Sinha
author_facet Maswanganyi, Shelter
Gusain, Rashi
Kumar, Neeraj
Fosso-Kankeu, Elvis
Waanders, Frans Boudewijn
Ray, Suprakas Sinha
author_sort Maswanganyi, Shelter
collection PubMed
description [Image: see text] Polycyclic aromatic hydrocarbons are a class of persistent organic water pollutants that raise serious concerns owing to their carcinogenicity and other negative impacts on humans and ecosystems. In this study, Bi(2)MoO(6)/reduced graphene oxide (rGO) nanocomposites were designed and prepared for the adsorption-assisted photodegradation of naphthalene molecules in an aqueous medium. The synthesized Bi(2)MoO(6) nanoplates and Bi(2)MoO(6)/rGO nanocomposites were characterized by X-ray diffraction, Fourier transform infrared, scanning electron microscopy, high-resolution transmission microscopy, X-ray photoelectron spectroscopy, ultraviolet spectroscopy, Brunauer–Emmett–Teller, and photoluminescence measurements. The photodegradation of naphthalene molecules was observed to assess the photocatalytic characteristics of the samples under visible light. The Bi(2)MoO(6)/rGO nanocomposites exhibited significantly improved photocatalytic efficiency compared to pure Bi(2)MoO(6). Among the nanocomposites, those containing 2 wt % rGO showed the best photocatalytic activity. The incorporation of rGO enhanced the visible light absorption and decreased the recombination rate of photogenerated charge carriers. Moreover, a Bi(2)MoO(6)/rGO nanocomposite showed excellent reusability for five cycles.
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spelling pubmed-82648452021-07-09 Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation Maswanganyi, Shelter Gusain, Rashi Kumar, Neeraj Fosso-Kankeu, Elvis Waanders, Frans Boudewijn Ray, Suprakas Sinha ACS Omega [Image: see text] Polycyclic aromatic hydrocarbons are a class of persistent organic water pollutants that raise serious concerns owing to their carcinogenicity and other negative impacts on humans and ecosystems. In this study, Bi(2)MoO(6)/reduced graphene oxide (rGO) nanocomposites were designed and prepared for the adsorption-assisted photodegradation of naphthalene molecules in an aqueous medium. The synthesized Bi(2)MoO(6) nanoplates and Bi(2)MoO(6)/rGO nanocomposites were characterized by X-ray diffraction, Fourier transform infrared, scanning electron microscopy, high-resolution transmission microscopy, X-ray photoelectron spectroscopy, ultraviolet spectroscopy, Brunauer–Emmett–Teller, and photoluminescence measurements. The photodegradation of naphthalene molecules was observed to assess the photocatalytic characteristics of the samples under visible light. The Bi(2)MoO(6)/rGO nanocomposites exhibited significantly improved photocatalytic efficiency compared to pure Bi(2)MoO(6). Among the nanocomposites, those containing 2 wt % rGO showed the best photocatalytic activity. The incorporation of rGO enhanced the visible light absorption and decreased the recombination rate of photogenerated charge carriers. Moreover, a Bi(2)MoO(6)/rGO nanocomposite showed excellent reusability for five cycles. American Chemical Society 2021-06-22 /pmc/articles/PMC8264845/ /pubmed/34250338 http://dx.doi.org/10.1021/acsomega.1c01296 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Maswanganyi, Shelter
Gusain, Rashi
Kumar, Neeraj
Fosso-Kankeu, Elvis
Waanders, Frans Boudewijn
Ray, Suprakas Sinha
Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation
title Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation
title_full Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation
title_fullStr Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation
title_full_unstemmed Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation
title_short Bismuth Molybdate Nanoplates Supported on Reduced Graphene Oxide: An Effective Nanocomposite for the Removal of Naphthalene via Adsorption–Photodegradation
title_sort bismuth molybdate nanoplates supported on reduced graphene oxide: an effective nanocomposite for the removal of naphthalene via adsorption–photodegradation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8264845/
https://www.ncbi.nlm.nih.gov/pubmed/34250338
http://dx.doi.org/10.1021/acsomega.1c01296
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