Up-Scalable Fabrication of SnO(2) with Multifunctional Interface for High Performance Perovskite Solar Modules

Tin dioxide (SnO(2)) has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells (PSCs). However, scalable fabrication of SnO(2) films with uniform coverage, desirable thickness and a low defect density in perovskite solar modules (PSMs) is still challenging. Here, we report preparation of high-quality large-area SnO(2) films by chemical bath deposition (CBD) with the addition of KMnO(4). The strong oxidizing nature of KMnO(4) promotes the conversion from Sn(II) to Sn(VI), leading to reduced trap defects and a higher carrier mobility of SnO(2). In addition, K ions diffuse into the perovskite film resulting in larger grain sizes, passivated grain boundaries, and reduced hysteresis of PSCs. Furthermore, Mn ion doping improves both the crystallinity and the phase stability of the perovskite film. Such a multifunctional interface engineering strategy enabled us to achieve a power conversion efficiency (PCE) of 21.70% with less hysteresis for lab-scale PSCs. Using this method, we also fabricated 5 × 5 and 10 × 10 cm(2) PSMs, which showed PCEs of 15.62% and 11.80% (active area PCEs are 17.26% and 13.72%), respectively. For the encapsulated 5 × 5 cm(2) PSM, we obtained a T(80) operation lifetime (the lifespan during which the solar module PCE drops to 80% of its initial value) exceeding 1000 h in ambient condition. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-021-00675-7.