A study of cation-dependent inverse hydrogen bonds and magnetic exchange-couplings in lanthanacarborane complexes

Ten lanthanacarborane complexes were synthesized to study the rare B−H(δ−)∙∙∙M(n+) inverse hydrogen bonds (IHBs). The average bonding energy of B−H(δ−)∙∙∙Ln(3+) is theoretically determined to be larger than 24 kJ/mol, which is comparable to moderately strong hydrogen bonds (21–56 kJ/mol). In additio...

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Detalles Bibliográficos
Autores principales: Jin, Peng-Bo, Luo, Qian-Cheng, Zhai, Yuan-Qi, Wang, Yi-Dian, Ma, Yan, Tian, Lei, Zhang, Xinliang, Ke, Chao, Zhang, Xu-Feng, Lv, Yi, Zheng, Yan-Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271178/
https://www.ncbi.nlm.nih.gov/pubmed/34278267
http://dx.doi.org/10.1016/j.isci.2021.102760

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271178/
https://www.ncbi.nlm.nih.gov/pubmed/34278267
http://dx.doi.org/10.1016/j.isci.2021.102760

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