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A study of cation-dependent inverse hydrogen bonds and magnetic exchange-couplings in lanthanacarborane complexes
Ten lanthanacarborane complexes were synthesized to study the rare B−H(δ−)∙∙∙M(n+) inverse hydrogen bonds (IHBs). The average bonding energy of B−H(δ−)∙∙∙Ln(3+) is theoretically determined to be larger than 24 kJ/mol, which is comparable to moderately strong hydrogen bonds (21–56 kJ/mol). In additio...
| Autores principales: | , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271178/ https://www.ncbi.nlm.nih.gov/pubmed/34278267 http://dx.doi.org/10.1016/j.isci.2021.102760 |