The Activating Effect of Strong Acid for Pd-Catalyzed Directed C–H Activation by Concerted Metalation-Deprotonation Mechanism

A computational study on the origin of the activating effect for Pd-catalyzed directed C–H activation by the concerted metalation-deprotonation (CMD) mechanism is conducted. DFT calculations indicate that strong acids can make Pd catalysts coordinate with directing groups (DGs) of the substrates mor...

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Detalles Bibliográficos
Autores principales: Jiang, Heming, Sun, Tian-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271562/
https://www.ncbi.nlm.nih.gov/pubmed/34279422
http://dx.doi.org/10.3390/molecules26134083

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271562/
https://www.ncbi.nlm.nih.gov/pubmed/34279422
http://dx.doi.org/10.3390/molecules26134083

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