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Supramolecular Chemistry: Host–Guest Molecular Complexes
In recent times, researchers have emphasized practical approaches for capturing coordinated and selective guest entrap. The physisorbed nanoporous supramolecular complexes have been widely used to restrain various guest species on compact supporting surfaces. The host–guest (HG) interactions in two-...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271753/ https://www.ncbi.nlm.nih.gov/pubmed/34208882 http://dx.doi.org/10.3390/molecules26133995 |
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author | Khan, Sadaf Bashir Lee, Shern-Long |
author_facet | Khan, Sadaf Bashir Lee, Shern-Long |
author_sort | Khan, Sadaf Bashir |
collection | PubMed |
description | In recent times, researchers have emphasized practical approaches for capturing coordinated and selective guest entrap. The physisorbed nanoporous supramolecular complexes have been widely used to restrain various guest species on compact supporting surfaces. The host–guest (HG) interactions in two-dimensional (2D) permeable porous linkages are growing expeditiously due to their future applications in biocatalysis, separation technology, or nanoscale patterning. The different crystal-like nanoporous network has been acquired to enclose and trap guest molecules of various dimensions and contours. The host centers have been lumped together via noncovalent interactions (such as hydrogen bonds, van der Waals (vdW) interactions, or coordinate bonds). In this review article, we enlighten and elucidate recent progress in HG chemistry, explored via scanning tunneling microscopy (STM). We summarize the synthesis, design, and characterization of typical HG structural design examined on various substrates, under ambient surroundings at the liquid-solid (LS) interface, or during ultrahigh vacuum (UHV). We emphasize isoreticular complexes, vibrant HG coordination, or hosts functional cavities responsive to the applied stimulus. Finally, we critically discuss the significant challenges in advancing this developing electrochemical field. |
format | Online Article Text |
id | pubmed-8271753 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-82717532021-07-11 Supramolecular Chemistry: Host–Guest Molecular Complexes Khan, Sadaf Bashir Lee, Shern-Long Molecules Review In recent times, researchers have emphasized practical approaches for capturing coordinated and selective guest entrap. The physisorbed nanoporous supramolecular complexes have been widely used to restrain various guest species on compact supporting surfaces. The host–guest (HG) interactions in two-dimensional (2D) permeable porous linkages are growing expeditiously due to their future applications in biocatalysis, separation technology, or nanoscale patterning. The different crystal-like nanoporous network has been acquired to enclose and trap guest molecules of various dimensions and contours. The host centers have been lumped together via noncovalent interactions (such as hydrogen bonds, van der Waals (vdW) interactions, or coordinate bonds). In this review article, we enlighten and elucidate recent progress in HG chemistry, explored via scanning tunneling microscopy (STM). We summarize the synthesis, design, and characterization of typical HG structural design examined on various substrates, under ambient surroundings at the liquid-solid (LS) interface, or during ultrahigh vacuum (UHV). We emphasize isoreticular complexes, vibrant HG coordination, or hosts functional cavities responsive to the applied stimulus. Finally, we critically discuss the significant challenges in advancing this developing electrochemical field. MDPI 2021-06-30 /pmc/articles/PMC8271753/ /pubmed/34208882 http://dx.doi.org/10.3390/molecules26133995 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Khan, Sadaf Bashir Lee, Shern-Long Supramolecular Chemistry: Host–Guest Molecular Complexes |
title | Supramolecular Chemistry: Host–Guest Molecular Complexes |
title_full | Supramolecular Chemistry: Host–Guest Molecular Complexes |
title_fullStr | Supramolecular Chemistry: Host–Guest Molecular Complexes |
title_full_unstemmed | Supramolecular Chemistry: Host–Guest Molecular Complexes |
title_short | Supramolecular Chemistry: Host–Guest Molecular Complexes |
title_sort | supramolecular chemistry: host–guest molecular complexes |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8271753/ https://www.ncbi.nlm.nih.gov/pubmed/34208882 http://dx.doi.org/10.3390/molecules26133995 |
work_keys_str_mv | AT khansadafbashir supramolecularchemistryhostguestmolecularcomplexes AT leeshernlong supramolecularchemistryhostguestmolecularcomplexes |