Solid-Phase “Self-Hydrolysis” of [Zn(NH(3))(4)MoO(4)@2H(2)O] Involving Enclathrated Water—An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer

An aerial humidity-induced solid-phase hydrolytic transformation of the [Zn(NH(3))(4)]MoO(4)@2H(2)O (compound 1@2H(2)O) with the formation of [(NH(4))(x)H((1−x))Zn(OH)(MoO(4))](n) (x = 0.92–0.94) coordination polymer (formally NH(4)Zn(OH)MoO(4), compound 2) is described. Based on the isostructural relationship, the powder XRD indicates that the crystal lattice of compound 1@2H(2)O contains a hydrogen-bonded network of tetraamminezinc (2+) and molybdate (2−) ions, and there are cavities (O(4)N(4)(μ-H(12)) cube) occupied by the two water molecules, which stabilize the crystal structure. Several observations indicate that the water molecules have no fixed positions in the lattice voids; instead, the cavity provides a neighborhood similar to those in clathrates. The @ symbol in the notation is intended to emphasize that the H(2)O in this compound is enclathrated rather than being water of crystallization. Yet, signs of temperature-dependent dynamic interactions with the wall of the cages can be detected, and 1@2H(2)O easily releases its water content even on standing and yields compound 2. Surprisingly, hydrolysis products of 1 were observed even in the absence of aerial humidity, which suggests a unique solid-phase quasi-intramolecular hydrolysis. A mechanism involving successive substitution of the ammonia ligands by water molecules and ammonia release is proposed. An ESR study of the Cu-doped compound 2 (2#dotCu) showed that this complex consists of two different Cu(2+)(Zn(2+)) environments in the polymeric structure. Thermal decomposition of compounds 1 and 2 results in ZnMoO(4) with similar specific surface area and morphology. The ZnMoO(4) samples prepared from compounds 1 and 2 and compound 2 in itself are active photocatalysts in the degradation of Congo Red dye. IR, Raman, and UV studies on compounds 1@2H(2)O and 2 are discussed in detail.