Cargando…
Selective β-Mono-Glycosylation of a C15-Hydroxylated Metabolite of the Agricultural Herbicide Cinmethylin Using Leloir Glycosyltransferases
[Image: see text] Cinmethylin is a well-known benzyl-ether derivative of the natural terpene 1,4-cineole that is used industrially as a pre-emergence herbicide in grass weed control for crop protection. Cinmethylin detoxification in plants has not been reported, but in animals, it prominently involv...
Autores principales: | Jung, Jihye, Schmölzer, Katharina, Schachtschabel, Doreen, Speitling, Michael, Nidetzky, Bernd |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8278484/ https://www.ncbi.nlm.nih.gov/pubmed/33973475 http://dx.doi.org/10.1021/acs.jafc.1c01321 |
Ejemplares similares
-
Controllable Iterative β-Glucosylation
from UDP-Glucose by Bacillus cereus Glycosyltransferase GT1: Application for the Synthesis of Disaccharide-Modified
Xenobiotics
por: Jung, Jihye, et al.
Publicado: (2021) -
Leloir Glycosyltransferases and Natural Product Glycosylation: Biocatalytic Synthesis of the C-Glucoside Nothofagin, a Major Antioxidant of Redbush Herbal Tea
por: Bungaruang, Linda, et al.
Publicado: (2013) -
Leloir glycosyltransferases enabled to flow synthesis: Continuous production of the natural C‐glycoside nothofagin
por: Liu, Hui, et al.
Publicado: (2021) -
Solvent Engineering for Nonpolar Substrate Glycosylation
Catalyzed by the UDP-Glucose-Dependent Glycosyltransferase UGT71E5:
Intensification of the Synthesis of 15-Hydroxy Cinmethylin β-d-Glucoside
por: Jung, Jihye, et al.
Publicado: (2023) -
Synthesis and herbicidal activity of optically active cinmethylin, its enantiomer, and C3-substituted cinmethylin analogs
por: Ogawa, Narihito, et al.
Publicado: (2023)