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Absolute configuration retention of a configurationally labile ligand during dynamic processes of thiolate protected gold clusters
Monolayer protected metal clusters are dynamic nanoscale objects. For example, the chiral Au(38)(2-PET)(24) cluster (2-PET: 2-phenylethylthiolate) racemizes at moderate temperature. In addition, ligands and metal atoms can easily exchange between clusters. Such processes are important for applicatio...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8278927/ https://www.ncbi.nlm.nih.gov/pubmed/34349915 http://dx.doi.org/10.1039/d1sc01702k |