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Mechanistic Insights into the Dual Directing Group-Mediated C–H Functionalization/Annulation via a Hydroxyl Group-Assisted M(III)-M(V)-M(III) Pathway

[Image: see text] The experimental investigations on the catalyst [Cp*Rh(OAc)(2) and Cp*Ir (OAc)(2))]-controlled [3 + 2] and [4 + 2] annulations of oximes with propargyl alcohols have been finished in our previous work and a supposed dual directing group-mediated reaction pathway has been deduced fo...

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Detalles Bibliográficos
Autores principales: Xu, Huiying, Bian, Mengyao, Zhou, Zhi, Gao, Hui, Yi, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8280669/
https://www.ncbi.nlm.nih.gov/pubmed/34278149
http://dx.doi.org/10.1021/acsomega.1c02183