The Effect of Added Ligands on the Reactions of [Ni(COD)(dppf)] with Alkyl Halides: Halide Abstraction May Be Reversible

[Image: see text] The reactions of dppf-nickel(0) with alkyl halides proceed via three-coordinate nickel(0) intermediates of the form [Ni(dppf)(L)]. The effects of the identity of the added ligand (L) on catalyst speciation and the rates of reactions of [Ni(COD)(dppf)] with alkyl halides have been i...

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Detalles Bibliográficos
Autores principales: Greaves, Megan E., Ronson, Thomas O., Maseras, Feliu, Nelson, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8288641/
https://www.ncbi.nlm.nih.gov/pubmed/34295014
http://dx.doi.org/10.1021/acs.organomet.1c00280

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8288641/
https://www.ncbi.nlm.nih.gov/pubmed/34295014
http://dx.doi.org/10.1021/acs.organomet.1c00280

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