Interplay between Electrolyte-Gated Organic Field-Effect Transistors and Surfactants: A Surface Aggregation Tool and Protecting Semiconducting Layer

[Image: see text] Molecular surfactants, which are based on a water-insoluble tail and a water-soluble head, are widely employed in many areas, such as surface coatings or for drug delivery, thanks to their capability to form micelles in solution or supramolecular structures at the solid/liquid interface. Electrolyte-gated organic field-effect transistors (EGOFETs) are highly sensitive to changes occurring at their electrolyte/gate electrode and electrolyte/organic semiconductor interfaces, and hence, they have been much explored in biosensing due to their inherent amplification properties. Here, we demonstrate that the EGOFETs and surfactants can provide mutual benefits to each other. EGOFETs can be a simple and complementary tool to study the aggregation behavior of cationic and anionic surfactants at low concentrations on a polarized metal surface. In this way, we have monitored the monolayer formation of cationic and anionic surfactants at the water/electrode interface with p-type and n-type devices, respectively. On the other hand, the operational stability of EGOFETs has been dramatically enhanced, thanks to the formation of a protective layer on top of the organic semiconductor by exposing it to a high concentration of a surfactant solution (above the critical micelle concentration). Stable performances were achieved for more than 10 and 2 h of continuous operation for p-type and n-type devices, respectively. Accordingly, this work points not only that EGOFETs can be applied to a wider range of applications beyond biosensing but also that these devices can effectively improve their long-term stability by simply treating them with a suitable surfactant.