Tandem Iridium-Catalyzed Decarbonylative C–H Activation of Indole: Sacrificial Electron-Rich Ketone-Assisted Bis-arylsulfenylation

[Image: see text] Described herein is a decarbonylative tandem C–H bis-arylsulfenylation of indole at the C2 and C4 C–H bonds through the use of pentamethylcyclopentadienyl iridium dichloride dimer ([Cp*IrCl(2)](2)) catalyst and disulfides. A new sacrificial electron-rich adamantoyl-directing group...

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Detalles Bibliográficos
Autores principales: Kathiravan, Subban, Anaspure, Prasad, Zhang, Tianshu, Nicholls, Ian A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289288/
https://www.ncbi.nlm.nih.gov/pubmed/33908788
http://dx.doi.org/10.1021/acs.orglett.1c00829

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289288/
https://www.ncbi.nlm.nih.gov/pubmed/33908788
http://dx.doi.org/10.1021/acs.orglett.1c00829

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