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Tandem Iridium-Catalyzed Decarbonylative C–H Activation of Indole: Sacrificial Electron-Rich Ketone-Assisted Bis-arylsulfenylation
[Image: see text] Described herein is a decarbonylative tandem C–H bis-arylsulfenylation of indole at the C2 and C4 C–H bonds through the use of pentamethylcyclopentadienyl iridium dichloride dimer ([Cp*IrCl(2)](2)) catalyst and disulfides. A new sacrificial electron-rich adamantoyl-directing group...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289288/ https://www.ncbi.nlm.nih.gov/pubmed/33908788 http://dx.doi.org/10.1021/acs.orglett.1c00829 |