Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters

[Image: see text] An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups...

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Autores principales: Suzuki, Minori, Kanemoto, Kazuya, Nakamura, Yu, Hosoya, Takamitsu, Yoshida, Suguru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289295/
https://www.ncbi.nlm.nih.gov/pubmed/33908784
http://dx.doi.org/10.1021/acs.orglett.1c01292
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author Suzuki, Minori
Kanemoto, Kazuya
Nakamura, Yu
Hosoya, Takamitsu
Yoshida, Suguru
author_facet Suzuki, Minori
Kanemoto, Kazuya
Nakamura, Yu
Hosoya, Takamitsu
Yoshida, Suguru
author_sort Suzuki, Minori
collection PubMed
description [Image: see text] An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.
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spelling pubmed-82892952021-07-20 Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters Suzuki, Minori Kanemoto, Kazuya Nakamura, Yu Hosoya, Takamitsu Yoshida, Suguru Org Lett [Image: see text] An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis. American Chemical Society 2021-04-28 2021-05-07 /pmc/articles/PMC8289295/ /pubmed/33908784 http://dx.doi.org/10.1021/acs.orglett.1c01292 Text en © 2021 The Authors. Published by American Chemical Society Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Suzuki, Minori
Kanemoto, Kazuya
Nakamura, Yu
Hosoya, Takamitsu
Yoshida, Suguru
Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
title Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
title_full Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
title_fullStr Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
title_full_unstemmed Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
title_short Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
title_sort palladium-catalyzed sulfinylation of aryl- and alkenylborons with sulfinate esters
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289295/
https://www.ncbi.nlm.nih.gov/pubmed/33908784
http://dx.doi.org/10.1021/acs.orglett.1c01292
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AT kanemotokazuya palladiumcatalyzedsulfinylationofarylandalkenylboronswithsulfinateesters
AT nakamurayu palladiumcatalyzedsulfinylationofarylandalkenylboronswithsulfinateesters
AT hosoyatakamitsu palladiumcatalyzedsulfinylationofarylandalkenylboronswithsulfinateesters
AT yoshidasuguru palladiumcatalyzedsulfinylationofarylandalkenylboronswithsulfinateesters

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