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Effect of the 2-R-Allyl and Chloride Ligands on the Cathodic Paths of [Mo(η(3)-2-R-allyl)(α-diimine)(CO)(2)Cl] (R = H, CH(3); α-diimine = 6,6′-Dimethyl-2,2′-bipyridine, Bis(p-tolylimino)acenaphthene)
[Image: see text] The new, formally Mo(II) complexes [Mo(η(3)-2-R-allyl)(6,6′-dmbipy)(CO)(2)Cl] (6,6′-dmbipy = 6,6′-dimethyl-2,2′-bipyridine; 2-R-allyl = allyl for R = H, 2-methallyl for R = CH(3)) and [Mo(η(3)-2-methallyl)(pTol-bian)(CO)(2)Cl] (pTol-bian = bis(p-tolylimino)acenaphthene) share, in t...
Autores principales: | Taylor, James O., Culpeck, Ryan, Chippindale, Ann M., Calhorda, Maria José, Hartl, František |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289335/ https://www.ncbi.nlm.nih.gov/pubmed/34295012 http://dx.doi.org/10.1021/acs.organomet.1c00038 |
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