Cargando…

Supramolecular packing of alkyl substituted Janus face all-cis 2,3,4,5,6-pentafluorocyclohexyl motifs

This study uses X-ray crystallography, theory and Langmuir isotherm analysis to explore the conformations and molecular packing of alkyl all-cis 2,3,4,5,6-pentafluorocyclohexyl motifs, which are prepared by direct aryl hydrogenations from alkyl- or vinyl-pentafluoroaryl benzenes. Favoured conformati...

Descripción completa

Detalles Bibliográficos
Autores principales:	Clark, Joshua L., Taylor, Alaric, Geddis, Ailsa, Neyyappadath, Rifahath M., Piscelli, Bruno A., Yu, Cihang, Cordes, David B., Slawin, Alexandra M. Z., Cormanich, Rodrigo A., Guldin, Stefan, O'Hagan, David
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8293821/ https://www.ncbi.nlm.nih.gov/pubmed/34349942 http://dx.doi.org/10.1039/d1sc02130c

Ejemplares similares

Janus All‐Cis 2,3,4,5,6‐Pentafluorocyclohexyl Building Blocks Applied to Medicinal Chemistry and Bioactives Discovery Chemistry
por: Clark, Joshua L., et al.
Publicado: (2021)

Fluorine‐Induced Pseudo‐Anomeric Effects in Methoxycyclohexanes through Electrostatic 1,3‐Diaxial Interactions
por: Piscelli, Bruno A., et al.
Publicado: (2020)

6-exo-trig Michael addition-lactonizations for catalytic enantioselective chromenone synthesis
por: Neyyappadath, Rifahath M., et al.
Publicado: (2017)

Janus Face All‐cis 1,2,4,5‐tetrakis(trifluoromethyl)‐ and All‐cis 1,2,3,4,5,6‐hexakis(trifluoromethyl)‐ Cyclohexanes
por: Yu, Cihang, et al.
Publicado: (2020)

Aryl (β,β′,β″-Trifluoro)-tert-butyl: A Candidate Motif for the Discovery of Bioactives
por: Dobson, Luca S., et al.
Publicado: (2023)

Metabolism and hydrophilicity of the polarised ‘Janus face’ all-cis tetrafluorocyclohexyl ring, a candidate motif for drug discovery
por: Rodil, Andrea, et al.
Publicado: (2018)

Selectively fluorinated cyclohexane building blocks: Derivatives of carbonylated all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexane
por: Ayoup, Mohammed Salah, et al.
Publicado: (2015)

2,3,4,5,6-Pentabromophenol
por: Betz, Richard, et al.
Publicado: (2008)

[3-Methoxy-5-(methoxycarbonyl)isoxazol-4-yl](4-methoxyphenyl)iodonium 2,2,2-trifluoroacetate
por: Abdul Manan, Mohd Abdul Fatah, et al.
Publicado: (2023)

Twin-Engine Janus Supramolecular Nanomotors with Counterbalanced Motion
por: Shao, Jingxin, et al.
Publicado: (2022)

1,10-Phenanthrolinium 2,3,4,5,6-pentafluorobenzoate–2,3,4,5,6-pentafluorobenzoic acid (1/2)
por: Zhang, Xiangdong, et al.
Publicado: (2009)

Isothiourea‐Catalyzed Acylative Kinetic Resolution of Tertiary α‐Hydroxy Esters
por: Qu, Shen, et al.
Publicado: (2020)

2,3,4,5,6-Pentafluoro-trans-cinnamic acid
por: Navarrete, Angélica, et al.
Publicado: (2013)

N-Benzyl-2,3,4,5,6-pentafluorobenzamide
por: Valkonen, Arto, et al.
Publicado: (2010)

Single enantiomer synthesis of α-(trifluoromethyl)-β-lactam
por: Jurčík, Václav, et al.
Publicado: (2011)

Synthesis of phosphonate and phostone analogues of ribose-1-phosphates
por: Nasomjai, Pitak, et al.
Publicado: (2009)

Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles
por: Marelli, Enrico, et al.
Publicado: (2016)

Supramolecular Packing Drives Morphological Transitions of Charged Surfactant Micelles
por: Schäfer, Ken, et al.
Publicado: (2020)

Ethyl 2-(2,3,4,5,6-Pentabromophenyl)acetate
por: Sauer, Anne M., et al.
Publicado: (2010)

Self-Assembled Alkylated Polyamine Analogs as Supramolecular Anticancer Agents
por: Sil, Diptesh, et al.
Publicado: (2022)

Prins fluorination cyclisations: Preparation of 4-fluoro-pyran and -piperidine heterocycles
por: Launay, Guillaume G, et al.
Publicado: (2010)

Three step synthesis of single diastereoisomers of the vicinal trifluoro motif
por: Brunet, Vincent A, et al.
Publicado: (2009)

Straightforward preparation of supramolecular Janus nanorods by hydrogen bonding of end-functionalized polymers
por: Han, Shuaiyuan, et al.
Publicado: (2020)

Probing Regio- and Enantioselectivity in the Formal [2 + 2] Cycloaddition of C(1)-Alkyl Ammonium Enolates with β- and α,β-Substituted Trifluoromethylenones
por: Wang, Yihong, et al.
Publicado: (2023)

The Effect of Branched Alkyl Chain Length on the Properties of Supramolecular Organogels from Mono-N-Alkylated Primary Oxalamides
por: Azyat, Khalid, et al.
Publicado: (2022)

Stereoselective α-fluoroamide and α-fluoro-γ-lactone synthesis by an asymmetric zwitterionic aza-Claisen rearrangement
por: Tenza, Kenny, et al.
Publicado: (2005)

The vicinal difluoro motif: The synthesis and conformation of erythro- and threo- diastereoisomers of 1,2-difluorodiphenylethanes, 2,3-difluorosuccinic acids and their derivatives
por: O'Hagan, David, et al.
Publicado: (2006)

The difluoromethylene (CF(2)) group in aliphatic chains: Synthesis and conformational preference of palmitic acids and nonadecane containing CF(2) groups
por: Wang, Yi, et al.
Publicado: (2014)

(E)-3-(2,3,4,5,6-Pentafluorostyryl)thiophene
por: Clément, Sébastien, et al.
Publicado: (2010)

1-[(2,3,4,5,6-Pentafluorophenyl)ethynyl]ferrocene
por: Zhang, Chan, et al.
Publicado: (2010)

Supramolecular Packing Controls H(2) Photocatalysis in Chromophore Amphiphile Hydrogels
por: Weingarten, Adam S., et al.
Publicado: (2015)

Supramolecular Self‐Assembly of β(3)‐Peptides Mediated by Janus‐Type Recognition Units
por: Kabata Glowacki, Selda, et al.
Publicado: (2020)

Spontaneous Patterning of Binary Ligand Mixtures on CdSe Nanocrystals: From Random to Janus Packing
por: Elimelech, Orian, et al.
Publicado: (2023)

Use of a New Non-Pyrophoric Liquid Aluminum Precursor for Atomic Layer Deposition
por: Xia, Xueming, et al.
Publicado: (2019)

Isothiourea-Catalyzed [2 + 2] Cycloaddition of C(1)-Ammonium Enolates and N-Alkyl Isatins
por: Abdelhamid, Yusra, et al.
Publicado: (2022)

Fluorinated cyclohexanes: Synthesis of amine building blocks of the all-cis 2,3,5,6-tetrafluorocyclohexylamine motif
por: Bykova, Tetiana, et al.
Publicado: (2017)

A Desilylative Approach to Alkyl Substituted C(1)‐Ammonium Enolates: Application in Enantioselective [2+2] Cycloadditions
por: Wang, Yihong, et al.
Publicado: (2022)

Hydrofluorination of Alkynes Catalysed by Gold Bifluorides
por: Nahra, Fady, et al.
Publicado: (2015)

4,4′-Bipyridine–2,3,4,5,6-pentafluorobenzoic acid (1/2)
por: Zhang, Xiangdong, et al.
Publicado: (2009)

The packing density of a supramolecular membrane protein cluster is controlled by cytoplasmic interactions
por: Merklinger, Elisa, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_envjl03o02eijcgs698lad6b0p