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Thermal Behavior of Oil Shale Pyrolysis under Low-Temperature Co-Current Oxidizing Conditions

[Image: see text] The thermal behavior of the Huadian oil shale during low-temperature co-current oxidizing pyrolysis was studied by lab-scale experiments under different basic pyrolysis temperatures and input gas flow rates. The results showed that, in the process of oil shale co-current oxidizing...

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Detalles Bibliográficos
Autores principales: Guo, Wei, Yang, Qinchuan, Zhang, Xu, Xu, Shaotao, Deng, Sunhua, Li, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8296611/
https://www.ncbi.nlm.nih.gov/pubmed/34308041
http://dx.doi.org/10.1021/acsomega.1c01875
Descripción
Sumario:[Image: see text] The thermal behavior of the Huadian oil shale during low-temperature co-current oxidizing pyrolysis was studied by lab-scale experiments under different basic pyrolysis temperatures and input gas flow rates. The results showed that, in the process of oil shale co-current oxidizing pyrolysis, the increasing input gas flow rates under the same basic pyrolysis temperatures can significantly enhance the heat generation of oil shale. Meanwhile, it can be seen from the temperature variation characteristics of oil shale that the heat released by the oxidation reaction of semicoke and oxygen is enough to support the thermal decomposition of organic matter without supplemental heating. Moreover, it can be concluded from the 92.06% effective recovery of shale oil that a high yield of oil without a significant loss can be achieved. Finally, compared with increasing basic pyrolysis temperatures, the increased input gas flow rates have a more obvious effect on improving the effective recovery of shale oil.