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A Tunable Multivariate Metal–Organic Framework as a Platform for Designing Photocatalysts
[Image: see text] Catalysts for photochemical reactions underlie many foundations in our lives, from natural light harvesting to modern energy storage and conversion, including processes such as water photolysis by TiO(2). Recently, metal–organic frameworks (MOFs) have attracted large interest withi...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8297731/ https://www.ncbi.nlm.nih.gov/pubmed/33900747 http://dx.doi.org/10.1021/jacs.1c01764 |
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author | Wang, Yang Lv, Hao Grape, Erik Svensson Gaggioli, Carlo Alberto Tayal, Akhil Dharanipragada, Aditya Willhammar, Tom Inge, A. Ken Zou, Xiaodong Liu, Ben Huang, Zhehao |
author_facet | Wang, Yang Lv, Hao Grape, Erik Svensson Gaggioli, Carlo Alberto Tayal, Akhil Dharanipragada, Aditya Willhammar, Tom Inge, A. Ken Zou, Xiaodong Liu, Ben Huang, Zhehao |
author_sort | Wang, Yang |
collection | PubMed |
description | [Image: see text] Catalysts for photochemical reactions underlie many foundations in our lives, from natural light harvesting to modern energy storage and conversion, including processes such as water photolysis by TiO(2). Recently, metal–organic frameworks (MOFs) have attracted large interest within the chemical research community, as their structural variety and tunability yield advantages in designing photocatalysts to address energy and environmental challenges. Here, we report a series of novel multivariate metal–organic frameworks (MTV-MOFs), denoted as MTV-MIL-100. They are constructed by linking aromatic carboxylates and AB(2)OX(3) bimetallic clusters, which have ordered atomic arrangements. Synthesized through a solvent-assisted approach, these ordered and multivariate metal clusters offer an opportunity to enhance and fine-tune the electronic structures of the crystalline materials. Moreover, mass transport is improved by taking advantage of the high porosity of the MOF structure. Combining these key advantages, MTV-MIL-100(Ti,Co) exhibits a high photoactivity with a turnover frequency of 113.7 mol(H2) g(cat.)(–1) min(–1), a quantum efficiency of 4.25%, and a space time yield of 4.96 × 10(–5) in the photocatalytic hydrolysis of ammonia borane. Bridging the fields of perovskites and MOFs, this work provides a novel platform for the design of highly active photocatalysts. |
format | Online Article Text |
id | pubmed-8297731 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical
Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-82977312021-07-23 A Tunable Multivariate Metal–Organic Framework as a Platform for Designing Photocatalysts Wang, Yang Lv, Hao Grape, Erik Svensson Gaggioli, Carlo Alberto Tayal, Akhil Dharanipragada, Aditya Willhammar, Tom Inge, A. Ken Zou, Xiaodong Liu, Ben Huang, Zhehao J Am Chem Soc [Image: see text] Catalysts for photochemical reactions underlie many foundations in our lives, from natural light harvesting to modern energy storage and conversion, including processes such as water photolysis by TiO(2). Recently, metal–organic frameworks (MOFs) have attracted large interest within the chemical research community, as their structural variety and tunability yield advantages in designing photocatalysts to address energy and environmental challenges. Here, we report a series of novel multivariate metal–organic frameworks (MTV-MOFs), denoted as MTV-MIL-100. They are constructed by linking aromatic carboxylates and AB(2)OX(3) bimetallic clusters, which have ordered atomic arrangements. Synthesized through a solvent-assisted approach, these ordered and multivariate metal clusters offer an opportunity to enhance and fine-tune the electronic structures of the crystalline materials. Moreover, mass transport is improved by taking advantage of the high porosity of the MOF structure. Combining these key advantages, MTV-MIL-100(Ti,Co) exhibits a high photoactivity with a turnover frequency of 113.7 mol(H2) g(cat.)(–1) min(–1), a quantum efficiency of 4.25%, and a space time yield of 4.96 × 10(–5) in the photocatalytic hydrolysis of ammonia borane. Bridging the fields of perovskites and MOFs, this work provides a novel platform for the design of highly active photocatalysts. American Chemical Society 2021-04-26 2021-05-05 /pmc/articles/PMC8297731/ /pubmed/33900747 http://dx.doi.org/10.1021/jacs.1c01764 Text en © 2021 The Authors. Published by American Chemical Society Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Wang, Yang Lv, Hao Grape, Erik Svensson Gaggioli, Carlo Alberto Tayal, Akhil Dharanipragada, Aditya Willhammar, Tom Inge, A. Ken Zou, Xiaodong Liu, Ben Huang, Zhehao A Tunable Multivariate Metal–Organic Framework as a Platform for Designing Photocatalysts |
title | A Tunable
Multivariate Metal–Organic Framework
as a Platform for Designing Photocatalysts |
title_full | A Tunable
Multivariate Metal–Organic Framework
as a Platform for Designing Photocatalysts |
title_fullStr | A Tunable
Multivariate Metal–Organic Framework
as a Platform for Designing Photocatalysts |
title_full_unstemmed | A Tunable
Multivariate Metal–Organic Framework
as a Platform for Designing Photocatalysts |
title_short | A Tunable
Multivariate Metal–Organic Framework
as a Platform for Designing Photocatalysts |
title_sort | tunable
multivariate metal–organic framework
as a platform for designing photocatalysts |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8297731/ https://www.ncbi.nlm.nih.gov/pubmed/33900747 http://dx.doi.org/10.1021/jacs.1c01764 |
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