Electrochemical Lithium Storage Performance of Molten Salt Derived V(2)SnC MAX Phase

MAX phases are gaining attention as precursors of two-dimensional MXenes that are intensively pursued in applications for electrochemical energy storage. Here, we report the preparation of V(2)SnC MAX phase by the molten salt method. V(2)SnC is investigated as a lithium storage anode, showing a high gravimetric capacity of 490 mAh g(−1) and volumetric capacity of 570 mAh cm(−3) as well as superior rate performance of 95 mAh g(−1) (110 mAh cm(−3)) at 50 C, surpassing the ever-reported performance of MAX phase anodes. Supported by operando X-ray diffraction and density functional theory, a charge storage mechanism with dual redox reaction is proposed with a Sn–Li (de)alloying reaction that occurs at the edge sites of V(2)SnC particles where Sn atoms are exposed to the electrolyte followed by a redox reaction that occurs at V(2)C layers with Li. This study offers promise of using MAX phases with M-site and A-site elements that are redox active as high-rate lithium storage materials. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-021-00684-6.