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Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes

[Image: see text] Alkynylcyclopropanes have found promising applications in both organic synthesis and medicinal chemistry but remain rather underexplored due to the challenges associated with their preparation. We describe a convenient two-step methodology for the alkynylcyclopropanation of alkenes...

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Detalles Bibliográficos
Autores principales: Mato, Mauro, Montesinos-Magraner, Marc, Sugranyes, Arnau R., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8299462/
https://www.ncbi.nlm.nih.gov/pubmed/34236835
http://dx.doi.org/10.1021/jacs.1c05422