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Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)

α-RuCl(3) is a major candidate for the realization of the Kitaev quantum spin liquid, but its zigzag antiferromagnetic order at low temperatures indicates deviations from the Kitaev model. We have quantified the spin Hamiltonian of α-RuCl(3) by a resonant inelastic x-ray scattering study at the Ru L...

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Autores principales: Suzuki, H., Liu, H., Bertinshaw, J., Ueda, K., Kim, H., Laha, S., Weber, D., Yang, Z., Wang, L., Takahashi, H., Fürsich, K., Minola, M., Lotsch, B. V., Kim, B. J., Yavaş, H., Daghofer, M., Chaloupka, J., Khaliullin, G., Gretarsson, H., Keimer, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8302668/
https://www.ncbi.nlm.nih.gov/pubmed/34301938
http://dx.doi.org/10.1038/s41467-021-24722-4
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author Suzuki, H.
Liu, H.
Bertinshaw, J.
Ueda, K.
Kim, H.
Laha, S.
Weber, D.
Yang, Z.
Wang, L.
Takahashi, H.
Fürsich, K.
Minola, M.
Lotsch, B. V.
Kim, B. J.
Yavaş, H.
Daghofer, M.
Chaloupka, J.
Khaliullin, G.
Gretarsson, H.
Keimer, B.
author_facet Suzuki, H.
Liu, H.
Bertinshaw, J.
Ueda, K.
Kim, H.
Laha, S.
Weber, D.
Yang, Z.
Wang, L.
Takahashi, H.
Fürsich, K.
Minola, M.
Lotsch, B. V.
Kim, B. J.
Yavaş, H.
Daghofer, M.
Chaloupka, J.
Khaliullin, G.
Gretarsson, H.
Keimer, B.
author_sort Suzuki, H.
collection PubMed
description α-RuCl(3) is a major candidate for the realization of the Kitaev quantum spin liquid, but its zigzag antiferromagnetic order at low temperatures indicates deviations from the Kitaev model. We have quantified the spin Hamiltonian of α-RuCl(3) by a resonant inelastic x-ray scattering study at the Ru L(3) absorption edge. In the paramagnetic state, the quasi-elastic intensity of magnetic excitations has a broad maximum around the zone center without any local maxima at the zigzag magnetic Bragg wavevectors. This finding implies that the zigzag order is fragile and readily destabilized by competing ferromagnetic correlations. The classical ground state of the experimentally determined Hamiltonian is actually ferromagnetic. The zigzag state is stabilized by quantum fluctuations, leaving ferromagnetism – along with the Kitaev spin liquid – as energetically proximate metastable states. The three closely competing states and their collective excitations hold the key to the theoretical understanding of the unusual properties of α-RuCl(3) in magnetic fields.
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spelling pubmed-83026682021-08-20 Proximate ferromagnetic state in the Kitaev model material α-RuCl(3) Suzuki, H. Liu, H. Bertinshaw, J. Ueda, K. Kim, H. Laha, S. Weber, D. Yang, Z. Wang, L. Takahashi, H. Fürsich, K. Minola, M. Lotsch, B. V. Kim, B. J. Yavaş, H. Daghofer, M. Chaloupka, J. Khaliullin, G. Gretarsson, H. Keimer, B. Nat Commun Article α-RuCl(3) is a major candidate for the realization of the Kitaev quantum spin liquid, but its zigzag antiferromagnetic order at low temperatures indicates deviations from the Kitaev model. We have quantified the spin Hamiltonian of α-RuCl(3) by a resonant inelastic x-ray scattering study at the Ru L(3) absorption edge. In the paramagnetic state, the quasi-elastic intensity of magnetic excitations has a broad maximum around the zone center without any local maxima at the zigzag magnetic Bragg wavevectors. This finding implies that the zigzag order is fragile and readily destabilized by competing ferromagnetic correlations. The classical ground state of the experimentally determined Hamiltonian is actually ferromagnetic. The zigzag state is stabilized by quantum fluctuations, leaving ferromagnetism – along with the Kitaev spin liquid – as energetically proximate metastable states. The three closely competing states and their collective excitations hold the key to the theoretical understanding of the unusual properties of α-RuCl(3) in magnetic fields. Nature Publishing Group UK 2021-07-23 /pmc/articles/PMC8302668/ /pubmed/34301938 http://dx.doi.org/10.1038/s41467-021-24722-4 Text en © The Author(s) 2021 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Suzuki, H.
Liu, H.
Bertinshaw, J.
Ueda, K.
Kim, H.
Laha, S.
Weber, D.
Yang, Z.
Wang, L.
Takahashi, H.
Fürsich, K.
Minola, M.
Lotsch, B. V.
Kim, B. J.
Yavaş, H.
Daghofer, M.
Chaloupka, J.
Khaliullin, G.
Gretarsson, H.
Keimer, B.
Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)
title Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)
title_full Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)
title_fullStr Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)
title_full_unstemmed Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)
title_short Proximate ferromagnetic state in the Kitaev model material α-RuCl(3)
title_sort proximate ferromagnetic state in the kitaev model material α-rucl(3)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8302668/
https://www.ncbi.nlm.nih.gov/pubmed/34301938
http://dx.doi.org/10.1038/s41467-021-24722-4
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