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All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode
Aluminum-ion batteries (AIBs) are promising next-generation batteries systems because of their features of low cost and abundant aluminum resource. However, the inferior rate capacity and poor all-climate performance, especially the decayed capacity under low temperature, are still critical challeng...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Springer Nature Singapore
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8302704/ https://www.ncbi.nlm.nih.gov/pubmed/34297240 http://dx.doi.org/10.1007/s40820-021-00682-8 |
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author | Hu, Yuxiang Huang, Hongjiao Yu, Deshuang Wang, Xinyi Li, Linlin Hu, Han Zhu, Xiaobo Peng, Shengjie Wang, Lianzhou |
author_facet | Hu, Yuxiang Huang, Hongjiao Yu, Deshuang Wang, Xinyi Li, Linlin Hu, Han Zhu, Xiaobo Peng, Shengjie Wang, Lianzhou |
author_sort | Hu, Yuxiang |
collection | PubMed |
description | Aluminum-ion batteries (AIBs) are promising next-generation batteries systems because of their features of low cost and abundant aluminum resource. However, the inferior rate capacity and poor all-climate performance, especially the decayed capacity under low temperature, are still critical challenges toward high-specific-capacity AIBs. Herein, we report a binder-free and freestanding metal–organic framework-derived FeS(2)@C/carbon nanotube (FeS(2)@C/CNT) as a novel all-climate cathode in AIBs working under a wide temperature window between −25 and 50 °C with exceptional flexibility. The resultant cathode not only drastically suppresses the side reaction and volumetric expansion with high capacity and long-term stability but also greatly enhances the kinetic process in AIBs with remarkable rate capacity (above 151 mAh g(−1) at 2 A g(−1)) at room temperature. More importantly, to break the bottleneck of the inherently low capacity in graphitic material-based all-climate AIBs, the new hierarchical conductive composite FeS(2)@C/CNT highly promotes the all-climate performance and delivers as high as 117 mAh g(−1) capacity even under −25 °C. The well-designed metal sulfide electrode with remarkable performance paves a new way toward all-climate and flexible AIBs. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-021-00682-8. |
format | Online Article Text |
id | pubmed-8302704 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Springer Nature Singapore |
record_format | MEDLINE/PubMed |
spelling | pubmed-83027042021-08-12 All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode Hu, Yuxiang Huang, Hongjiao Yu, Deshuang Wang, Xinyi Li, Linlin Hu, Han Zhu, Xiaobo Peng, Shengjie Wang, Lianzhou Nanomicro Lett Article Aluminum-ion batteries (AIBs) are promising next-generation batteries systems because of their features of low cost and abundant aluminum resource. However, the inferior rate capacity and poor all-climate performance, especially the decayed capacity under low temperature, are still critical challenges toward high-specific-capacity AIBs. Herein, we report a binder-free and freestanding metal–organic framework-derived FeS(2)@C/carbon nanotube (FeS(2)@C/CNT) as a novel all-climate cathode in AIBs working under a wide temperature window between −25 and 50 °C with exceptional flexibility. The resultant cathode not only drastically suppresses the side reaction and volumetric expansion with high capacity and long-term stability but also greatly enhances the kinetic process in AIBs with remarkable rate capacity (above 151 mAh g(−1) at 2 A g(−1)) at room temperature. More importantly, to break the bottleneck of the inherently low capacity in graphitic material-based all-climate AIBs, the new hierarchical conductive composite FeS(2)@C/CNT highly promotes the all-climate performance and delivers as high as 117 mAh g(−1) capacity even under −25 °C. The well-designed metal sulfide electrode with remarkable performance paves a new way toward all-climate and flexible AIBs. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-021-00682-8. Springer Nature Singapore 2021-07-23 /pmc/articles/PMC8302704/ /pubmed/34297240 http://dx.doi.org/10.1007/s40820-021-00682-8 Text en © The Author(s) 2021 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Hu, Yuxiang Huang, Hongjiao Yu, Deshuang Wang, Xinyi Li, Linlin Hu, Han Zhu, Xiaobo Peng, Shengjie Wang, Lianzhou All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode |
title | All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode |
title_full | All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode |
title_fullStr | All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode |
title_full_unstemmed | All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode |
title_short | All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived FeS(2)@C/CNT Cathode |
title_sort | all-climate aluminum-ion batteries based on binder-free mof-derived fes(2)@c/cnt cathode |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8302704/ https://www.ncbi.nlm.nih.gov/pubmed/34297240 http://dx.doi.org/10.1007/s40820-021-00682-8 |
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